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Question

In which of the following species central atom is not surrounded by exactly 8 valence electrons ?

A
BF4
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B
NCl3
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C
PCl+4
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D
SF4
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Solution

The correct option is D SF4
In SF4 central sulphur atom has sp3d hybridisation. Sulphur atom has 6 valence electrons around them and four 4 electrons are donated by the F atom during the covalent bond formation.
So the total number of electrons around the central sulphur atom will be (6+4)=10 electrons.
So, option D is correct.

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