The mole fraction of Iodine in solution is 0.25.
1 mole of solution will have 0.25 moles of iodine and 1−0.25=0.75 moles of benzene. The molecular weight of benzene is 78 g/mol.
The mass of benzene =0.75mol×78g/mol=58.5g
Convert the unit of mass from g to kg.
58.5g×1kg1000g=0.0585kg
The molality of the solution =0.25mol0.0585kg=4.27m