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Question

Iodobenzene is prepared from aniline (C6H5NH2) in a two step process as shown here:
C6H5NH2+HNO2+HClC6H5N+2Cl+2H2O
C6H5N+2Cl+KlC6H5I+N2+KCl
In an actual preparation, 9.30 g of aniline was converted to 12.32 g of iodobenzene. The percentage yield of iodobenzene is:

A
8%
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B
50%
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C
25%
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D
80%
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Solution

The correct option is C 80%
1 mole of C6H5NH2(123g) = 1 mol of C6H5I(204g)
9.3 g aniline will give =(204123×9.3)g iodobenzene
= 15.424 g idoboenzene

% yield =ActualamountofproductCalculatedamountofproduct×100

=12.3215.424×100=80%

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