Ionisation isomerism is possible in:

[C o (N H_{3})_{6}] C l_{3}

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[C o (N H_{3})_{3} C l_{3}]

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[C o (N H_{3})_{5} C l] B r

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[C o (H_{2} O)_{3} C l_{3}]

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Solution

The correct option is C $[C o (N H_{3})_{5} C l] B r$
Ionisation Isomerism:
Isomers in which the ligands exchange their place with an anion or neutral molecule which was originally outside the coordination complex are ionisation isomers. The central ion and the other ligands are identical.

$[C o (N H_{3})_{5} C l] B r \Rightarrow [C o (N H_{3})_{5} B r] C l$

$∴$ Answer is option C.

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Similar questions

Q. Which is right combination?

(a) Hydrate isomerism-

[C o (H_{2} O)_{3} C l_{3}] 3 H_{2} O

and

[C o (H_{2} O)_{6}] C l_{3}

(b) Ionisation isomerism-

[C o (N H_{3})_{5} B r] S O_{4}

and

[C o (N H_{3})_{5} S O_{4}] B r

M C l_{2} B r_{2}

Arrange the following complexes in the increasing order of conductivity of their solution

$[C o (N H_{3})_{3} C l_{3}], [C o (N H_{3})_{4} C l_{2}] C l, [C o (N H_{3})_{6}] C l_{3}, [C o (N H_{3})_{5} C l] C l_{2}$

Q. The correct order of the following complexes according to increasing conductivity of their solutions will be:
(i)

[C o (N H_{3})_{3} C l_{3}]

(ii)

[C o (N H_{3})_{4} C l_{2}] C l

(iii)

[C o (N H_{3})_{6}] C l_{3}

(iv)

[C o (N H_{3})_{5} C l] C l_{2}

Q. Which isomerism is shown by

[C o (N H_{3})_{6}] C l_{3}

. Write name?

Q. Which of the following does not give a precipitate of

A g C l

with

A g N O_{3}

solution?

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