K2CO3 cannot be prepared by Solvay's process because:
A
KHCO3 is less soluble than NaHCO3
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B
KHCO3 is too soluble to be precipitated by KCl and NH4HCO3
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C
K2CO3 is too soluble to be precipitated by KCl
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D
K2CO3 is less soluble than Na2CO3
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Solution
The correct option is AKHCO3 is too soluble to be precipitated by KCl and NH4HCO3 Solvay process cannot be used to prepare potassium carbonate. This is because unlike sodium bicarbonate, potassium bicarbonate is fairly soluble in water and does not precipitate out.
i.e. KHCO3 is too soluble to be precipitated by KCl and NH4HCO3.