Kc for 2SO2+O2⇌2SO3 in a 10lit flask at certain T is 100lit.mol−1. Now , if equilibrium pressures of SO2 and SO3 are equal , then mass of O2 present at equilibrium is:
A
6.4g
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B
12.8g
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C
3.2g
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D
16g
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Solution
The correct option is C3.2g
It is given that the equilibrium pressures of SO2 and SO3 are equal. Therefore, the number of moles of SO2 and SO3 are also equal at equilibrium.
a−2x=2x
a=4x
Kc=[SO3]2[SO2]2[O2]
100=1[O2] (Since concentration of SO3 and SO2 are equal)
100=10a−x=103x
3x=0.1
Number of moles of O2 at equilibrium are a−x=3x=0.1