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Question

Kc for 2SO2+O22SO3 in a 10 lit flask at certain T is 100 lit.mol1. Now , if equilibrium pressures of SO2 and SO3 are equal , then mass of O2 present at equilibrium is:

A
6.4g
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B
12.8g
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C
3.2g
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D
16g
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Solution

The correct option is C 3.2g
  • It is given that the equilibrium pressures of SO2 and SO3 are equal. Therefore, the number of moles of SO2 and SO3 are also equal at equilibrium.
  • a2x=2x
a=4x
  • Kc=[SO3]2[SO2]2[O2]
  • 100=1[O2] (Since concentration of SO3 and SO2 are equal)

100=10ax=103x
3x=0.1
  • Number of moles of O2 at equilibrium are ax=3x=0.1
  • Mass of O2=0.1×32=3.2g

1116492_1154599_ans_c30f283e79cd4cc0b1f8a49a89b79c0a.jpg

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