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Question

Ksp value of Al(OH)3 and Zn(OH)2 are 8.5 × 1023 and 1.8 × 1014 respectively. If NH4OH is added in a solution of Al+3 and Zn+2 which will precipitate earlier:

A
Al(OH)3
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B
Zn(OH)2
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C
Both together
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D
None will precipitate
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Solution

The correct option is A Al(OH)3
Ksp of Al(OH)3=8.5×1023
Ksp of Zn(OH)2=1.8×1014
After adding of NH4OH in the solution of Al+3 and Zn+2, Al(OH)3 will precipitatet earlier because its solubility product value is less then Zn(OH)2.

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