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Question

Ksp values for silver bromide, silver chloride and silver iodide are 5×1013mol2 dm6,2×1010mol2 dm6,8×1017mol2 dm6 respectively. the order of solubility of these silver salts is:

A
AgCl>AgBr>AgI
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B
AgI>AgBr>AgCl
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C
AgCl>AgI>AgBr
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D
AgI>AgCl>AgBr
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Solution

The correct option is D AgCl>AgBr>AgI
Solubility for AgCl,AgBr and AgI (S2=Ksp)
SAgBr=0.707×106
SAgCl=1.4×105
SAgI=0.9×108
So solubility order:AgCl>AgBr>AgI

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