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Question

[Cr(NH3)6][Cr(SCN)6] and [Cr(NH3)2(SCN)4][Cr(NH3)4(SCN)2] are the examples of what type of isomerism?

A
Ionisation isomerism
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B
Linkage isomerism
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C
Coordination isomerism
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D
Solvate isomerism
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Solution

The correct option is C Coordination isomerism

Coordination isomerism is a form of structural isomerism in which the composition of the complex ion varies. In a coordination isomer the total ratio of ligand to metal remains the same, but the ligands attached to a specific metal ion change. Examples of a complete series of coordination isomers require at least two metal ions and sometimes more.

For example, a solution containing ([Co(NH3)6]3+ and [Cr(CN)6]3−) is a coordination isomer with a solution containing [Cr(NH3)6]3+ and [Co(CN)6]3−


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