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Oxidation of Alkyl Side Chain

2 CH 3 KMnO 4...

Question

List-I contains questions related to reaction sequence and List-II contains their answers.

Which of the following options has the correct combination considering reaction in List-I and their product(s) in List-II?

I I \to P; I V \to T

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I I \to S; I V \to U

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I I \to P; I V \to T

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I I \to S; I V \to T

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Solution

The correct option is D $I I \to S; I V \to T$

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(C H_{3})_{3} C - C H = C H_{2} (A) H C l - - \to B + C

C_{6} H_{13} C l

B a l c . K O H - ----- \to △ D

C t - B u - O N a - ------ \to △ A

D O_{3} / H_{2} O - ---- \to Z n E

A O_{3} / H_{2} O - ---- \to M e_{2} S F + G

F + G c o n c N a O H - ------ \to H C O O N a + H

G c o n c N a O H - ------ \to H + J

H 1. c o n c H_{2} S O_{4} / △ - --------- \to 2. O_{3} / H_{2} O / Z n E + K

\begin{matrix} List - I & List - II (I)Which compound(s) can perform cannizzaro & (P) K reaction but not Aldol condensation reaction? (II) Which compound(s) when heated with conc & (Q) A H_{2} S O_{4} give(s) mesitylene? (III) Which compound(s) performed rearrangement & (R) G of 1,2-methyl shift during reaction? (IV) Which compound(s) can perform Aldol & (S) H condensation reaction but no Cannizzaro reaction when treated with dilute NaOH? (T) E (U) F \end{matrix}

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