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B
a−q,s;b−p,s;c−p,r;d−q,s
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C
a−q,r;b−p,r;c−p,r;d−p,s
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D
a−q,s;b−p,r;c−p,s;d−q,s
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Solution
The correct option is Aa−q,s;b−p,r;c−p,r;d−q,s (a)is a deactivating group due to −Meffect and therefore is a meta directing.
(b)is an activating group due to +M effect and hence is an ortho-para directing group.
(c)is an activating group due to +M effect and hence is an ortho-para directing group.
(d)is a deactivating group due to −M effect and hence is a meta directing group.