When the oxidation number of C increases, it undergoes oxidation and when the oxidation number of C decreases, it undergoes reduction. If there is no change in the oxidation number of C, then there is neither reduction nor oxidation.
(A) −4CH4⟶−2CH3OH
(Increase in oxidation number from -4 to -2) (Oxidation)
(B) 0CH2Cl2⟶0CH2O
(Oxidation number is zero for both) (Neither)
(C) −2CH2=−2CH2⟶H3−3C−−3CH3
(Decrease in oxidation number from -2 to -3 for both C) (Reduction)
(D) The oxidation number of both C's has change one from −1 to −3 and in the other from −1 to +1.
Thus, the average value is compared for both reactant and product, which is −1. It has remained unchanged, so it is neither.
C2H2⟶CH3CHO
2x+2=0 2x+4−2=0
x=−1 x=−1