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Question

Match the following reactions (in Column I) with processes (Column II).

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Solution

When the oxidation number of C increases, it undergoes oxidation and when the oxidation number of C decreases, it undergoes reduction. If there is no change in the oxidation number of C, then there is neither reduction nor oxidation.
(A) 4CH42CH3OH
(Increase in oxidation number from -4 to -2) (Oxidation)
(B) 0CH2Cl20CH2O
(Oxidation number is zero for both) (Neither)
(C) 2CH2=2CH2H33C3CH3
(Decrease in oxidation number from -2 to -3 for both C) (Reduction)
(D) The oxidation number of both C's has change one from 1 to 3 and in the other from 1 to +1.
Thus, the average value is compared for both reactant and product, which is 1. It has remained unchanged, so it is neither.
C2H2CH3CHO
2x+2=0 2x+42=0
x=1 x=1

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