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Question

Match the terms mentioned in Column I with the terms in Column II.

Column I Column II
A

Carbocation

(i)

Cyclohexane and 1-hexene

B

Nucleophile

(ii)

Conjugation of electrons of CH σ bond with empty p- orbital present at adjacent positively charged carbon.

C Hyperconjugation (iii)

sp2 hybridized carbon with empty p−orbital

D

Isomers

(iv)

Ethyne

E

sp hybridization

(v)

Species that can receive a pair of electrons

F

Electrophile

(vi)

Species that can supply a pair of electrons


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Solution

(A) Carbocation :

It is an electron deficient species having sp2 hybridised carbon with an empty p-orbital

Hence, the correct match is:
(A)(iii)

(B) Nucleophile :

It is an electron rich species which have negative charge or lone pair of electrons for donation to electrophiles. So, it can supply pairs of electrons.

Hence, the correct match is:

(B)(vi)

(C) Hyper conjugation :

It involves the conjugation of CH σ bond with empty p-orbital present at adjacent positively charged carbon.

Hence, the correct match is:
(C)(ii)

(D) Isomers :

Isomers are molecules of the same formula but having a different arrangement of their atoms. So, given two structures are isomers.



Hence, the correct match is :
(D)(i)

(E) sp hybridisation :

In ethyne molecule, all carbons are sp hybridised

Hence, the correct match is :
(E)(iv)

(F) Electrophile :

It is an electron deficient species. It can receive a pair of electrons from any electron rich species.

Hence, the correct match is :

(F)(v)

So, the correct matches can be represented as:
(A)(iii) , (B)(vi) , (C)(ii) , (D)(i) , (E)(iv) , (F)(v) .


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