Match the terms mentioned in Column I with the terms in Column II.
Column I | Column II | ||
A |
Carbocation |
(i) |
Cyclohexane and 1-hexene |
B |
Nucleophile |
(ii) |
Conjugation of electrons of C−H σ bond with empty p- orbital present at adjacent positively charged carbon. |
C | Hyperconjugation | (iii) |
sp2 hybridized carbon with empty p−orbital |
D |
Isomers |
(iv) |
Ethyne |
E |
sp hybridization |
(v) |
Species that can receive a pair of electrons |
F |
Electrophile |
(vi) |
Species that can supply a pair of electrons |
(A) Carbocation :
It is an electron deficient species having sp2 hybridised carbon with an empty p-orbital
Hence, the correct match is:
(A)→(iii)
(B) Nucleophile :
It is an electron rich species which have negative charge or lone pair of electrons for donation to electrophiles. So, it can supply pairs of electrons.
Hence, the correct match is:
(B)→(vi)
(C) Hyper conjugation :
It involves the conjugation of C−H σ bond with empty p-orbital present at adjacent positively charged carbon.
Hence, the correct match is:
(C)→(ii)
(D) Isomers :
Isomers are molecules of the same formula but having a different arrangement of their atoms. So, given two structures are isomers.
Hence, the correct match is :
(D)→(i)
(E) sp hybridisation :
In ethyne molecule, all carbons are sp hybridised
Hence, the correct match is :
(E)→(iv)
(F) Electrophile :
It is an electron deficient species. It can receive a pair of electrons from any electron rich species.
Hence, the correct match is :
(F)→(v)
So, the correct matches can be represented as:
(A)→(iii) , (B)→(vi) , (C)→(ii) , (D)→(i) , (E)→(iv) , (F)→(v) .