Methyl ester reacts with EtMgBr to give 3o alcohol (figure). The ester is:
A
Methyl propanoate
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B
Methyl butanoate
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C
Methyl ethanoate
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D
Methyl formate
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Solution
The correct option is B Methyl butanoate The ester is Methyl butanoate. It reacts with 2 moles of ethyl magnesium bromide to form the tert alcohol. 3o alcohol is shown in the first figure, with two (Et) Group obtained from G.R. Therefore, (Pr−) group has come from the ester. So, the ester is given in second figure (methyl butanoate). Hence, the answer is (B).