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Question

Methylene blue, from its aqueous solution, is absorbed on activated charcoal 25 C. For this process, the correct statement is

A
the absorption requires activation at 25 C
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B
the absorption is accompained by a decreases in enthalpy
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C
the absorption increases with increase of temperature
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D
the absorption is irreversible.
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Solution

The correct option is B the absorption is accompained by a decreases in enthalpy

Physical absorption takes place with decrease in enthalpy thus exothermic change. It is physical absorption and does not require activation. Thus, (a) is correct.
Being physical absorption ΔH<0 thus, (b) is correct. Exothermic reaction is favoured at low temperature thus (c) is incorrect. Physical absorption is always reversible, thus (d) is incorrect.


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