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Question

MnO24 (1 mole) in neutral aqueous medium is disproportionate to:

A
2/3 mole of MnO4 and 1/3 mole of MnO2
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B
1/3 mole of MnO4 and 2/3 mole of MnO2
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C
1/3 mole of Mn2O7 and 1/3 mole of MnO2
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D
2/3 mole of Mn2O7 and 1/3 mole of MnO2.
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Solution

The correct option is A 2/3 mole of MnO4 and 1/3 mole of MnO2
3MnO24neutralaqeousmediumMnO2+2MnO4+O2
MnO24neutralaqeousmedium13MnO2+23MnO4+13O2
In neutral aqeous medium, MnO24 disproportionates to give 13mole MnO2 and 23mole MnO4.

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