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Question

MnO2+2KClO3K2MnO4+Cl2+2O2
Cl2+KMnO42KCl+MnO2+O2
Each reaction takes place to the extent of 50%. 11.2 L of O2 at STP is obtained from KClO3 of amount equal to :

A
4 mol
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B
1.12 mol
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C
1.33 mol
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D
2.66 mol
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Solution

The correct option is B 4 mol
The balanced reactions are as follows:
MnO2+2KClO3K2MnO4+Cl2+2O2
Cl2+KMnO42KCl+MnO2+O2
According to the balanced reaction,
11.2 L of O2 (0.5 mol) =1 mole Cl2=4 mol KClO3
50% yield 50% yield

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