The balanced chemical equation is as given below:
MnO2+4HCl⟶MnCl2+2H2O+Cl2
1mol4mol
0.86mol 48.2g=1.32mol
HCl required by 0.86 mol MnO2=3.44mol
but HCl taken =1.32mol
Thus, HCl is the limiting reactant.
Thus, Cl2formed=14×1.32
=0.33molCl2
=23.43g
Hence, 23 g of chlorine will be produced.