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Question

Most reactive halide towards SN1 reaction is:

A
n-butyl chloride
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B
sec-butyl chloride
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C
tert-butyl chloride
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D
Allyl chloride
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Solution

The correct option is A n-butyl chloride
Organic compounds are more reactive towards SN1, if the carbocation is stable compared to others.
Here, in allyl chloride CH2=CHCH2Cl the cation formed is CH2=CHCH2CH2CH=CH2 is stabilized by equivalent resonance. So, allyl chloride has high reactivity towards SN1.

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