The pair(s) of coordination complexes/ions exhibiting the same kind of isomerism is(are)

[C O B r_{2} C l_{2}]^{2 -} and [P t B r_{2} C l_{2}]^{2 -}

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[C r (N H_{3})_{5} C l] C l_{2} and [C r (N H_{3})_{4} C l_{2}] C l

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[P t (N H_{3})_{3}] (N O_{3})] C l and [P t (N H_{3})_{3} C l] B r

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[C o (N H_{3})_{4} C l_{2}]^{+} and [P t (N H_{3})_{2} (H_{2} O) C l]^{+}

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Solution

The correct option is D $[C o (N H_{3})_{4} C l_{2}]^{+} and [P t (N H_{3})_{2} (H_{2} O) C l]^{+}$
The pair of complex ions $[C o (N H_{3})_{4} C l_{2}]^{+}$ and $[P t (N H_{3})_{2} (H_{2} O) C l]^{+}$ show geometrical isomerism. The pair of complexes $[P t (N H_{3})_{3} (N O_{3})] C l and [P t (N H_{3})_{3} C l] B r$ show ionisation isomerism. The other pairs given do not have same type of isomerism.

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Similar questions

Which of the following pairs of complexes are isomeric with each other but their aqueous solutions exhibit different molar conductivities?

[C o (N H_{3})_{4} B r_{2}] C l

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