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Question

N2 + O22NO,K1;
(12)N2+(12)O2NO,K2;
2NON2+O2;K3;
NO(12)N2+(12)O2;K4
Correct relation(s) between K1,K2,K3, and K4 is/are :

A
K1×K3=1
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B
K1×K4=1
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C
K3×K2=1
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D
none
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Solution

The correct options are
A K1×K3=1
B K1×K4=1
C K3×K2=1
N2 + O22NO,K1---------(1)
(12)N2+(12)O2NO,K2 -------------(2)
2NON2+O2;K3 ---------------(3)
NO(12)N2+(12)O2;K4 -----------------(4)
Reaction 3 is obtained by reversing the 1st reaction.
Hence, K1×K3=1
Reaction 1 is obtained by dividing reaction 1 by 2 and reversing it.
Hence, K1×K3=1
Reaction 3 is obtained by dividing reaction 2 by two and then reversing it.
Hence, K3×K2=1

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