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Question

The formation of cyanohydrin from acetone is which type of reaction?

A
Nucelophilic addition reaction
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B
Electrophilic substitution reaction
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C
Electrophilic addition reaction
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D
Nucelophilic substitution reaction
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Solution

The correct option is A Nucelophilic addition reaction
Cyanohydrin formation:


This reaction is nucleophilic addition reaction.
Step (i): The nucleophilic carbon in the cyanide adds to the electrophilic carbon in the polar carbonyl group, electrons from the C=O move to the electronegative O creating an intermediate alkoxide.
Step (ii): An acid/ base reaction protonation of the alkoxide oxygen creates the cyanohydrin product.

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