If the molar conductance values of Ca2+ and Cl− at infinite dilution are respectively 118.88×10−4cm2mhomol−1 and 77.66×10−4cm2mhomol−1, then that of CaCl2 is (cm2mhomol−1)
A
118.88×10−4
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B
196.21×10−4
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C
154.66×10−4
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D
273.54×10−4
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Solution
The correct option is D273.54×10−4 Λ∘m(CaCl2)=Λ∘m(Ca2+)+2Λ∘m(Cl−) =118.88×10−4+2(77.33×10−4) =273.54×10−4cm2mhomol−1