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Question

If the molar conductance values of Ca2+ and Cl at infinite dilution are respectively 118.88×104cm2 mho mol1 and 77.66×104cm2 mho mol1, then that of CaCl2 is (cm2 mho mol1)

A
118.88×104
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B
196.21×104
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C
154.66×104
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D
273.54×104
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Solution

The correct option is D 273.54×104
Λm(CaCl2)=Λm(Ca2+)+2Λm(Cl)
=118.88×104+2(77.33×104)
=273.54×104 cm2 mho mol1

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