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Question

Na2S+Na2[Fe(CN)5NO]X(purplecolor)
How many axial d-orbitals are involved in hybridization of X ?

A
1
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B
3
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C
2
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D
0
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Solution

The correct option is B 2
here X is,
Na4[Fe(CN)5(NOS)]
+2
so Fe+2=d6 , due to strong ligand pairing happens and low spin complex forms.
So it have zero unpaired electron and zero magnetic moment.
Fe=d2sp3 hybridization so two d-orbitals (only axial) involved in hybridization.
354388_309594_ans.jpg

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