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Question

Na2S+Na2[Fe(CN)5NO]X(purplecolor)

What is the formula of X?

A
Fe4[Fe(CN)6]
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B
[Fe(H2O)5NO]SO4
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C
[Fe(H2O)2NO]SO4
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D
Na4[Fe(CN)5(NOS)]
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Solution

The correct option is B Na4[Fe(CN)5(NOS)]
With sodium nitroprusside solution, ionic sulphide gives a purple colour in alkaline medium.

Na2S+Na2[Fe(CN)5NO]Na4[Fe(CN)5NOS]Purple colour

Here X is Na4[Fe(CN)5(NOS)].

Option (D) is correct.


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