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Nomenclature of Alcohols

Name the foll...

Question

Name the following halides according to $I U P A C$ system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:
i) $(C H_{3})_{2} C H C H (C l) C H_{3}$ ii) $C H_{3} C H_{2} C H (C H_{3}) C H (C_{2} H_{5}) C l$
iii) $C H_{3} C H_{2} C (C H_{3})_{2} C H_{2} I$ iv) $(C H_{3})_{3} C C H_{2} C H (B r) C_{6} H_{5}$
v) $C H_{3} C H (C H_{3}) C H (B r) C H_{3}$ vi) $C H_{3} C (C_{2} H_{5})_{2} C H_{2} B r$
vii) $C H_{3} C (C l) (C_{2} H_{5}) C H_{2} C H_{3}$ viii) $C H_{3} C H = C (C l) C H_{2} C H (C H_{3})_{2}$
ix) $C H_{3} C H = C H C (B r) (C H_{3})_{2}$ x) $p - C l C_{6} H_{4} C H_{2} C H (C H_{3})_{2}$
xi) $m - C l C H_{2} C_{6} H_{4} C H_{2} C (C H_{3})_{3}$ xii) $o - B r - C_{6} H_{4} C H (C H_{3}) C H_{2} C H_{3}$

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Solution

The IUPAC names of various compounds are given below in order:

(1) 2-Chloro-3-methylbutane (secondary alkyl halide)
(ii) 3-Chloro-4-methylhexane (secondary alkyl halide)
(iii) 1-Iodo-2,2-dimethylbutane (primary alkyl halide)
(iv) 1-Bromo-3,3-dimethyl-1-phenylbutane (secondary benzyl halide)
(v) 2-Bromo-3-methylbutane (secondary alkyl halide)
(vi) 1-Bromo-2-ethyl-2-methylbutane (primary alkyl halide)
(vii) 3-Chloro-3-methylpentane (tertiary alkyl halide)
(viii) 3-Chloro-5-methylhex-2-ene (vinyl halide)
(ix) 4-Bromo-4-methylpent-2-ene (allyl halide)
(x) 1-Chloro-4-(2-methylpropyl) benzene (aryl halide)
(xi) 1-Chloromethyl-3-(2,2-dimethylpropyl) benzene (primary benzyl halide)
(xii) 1-Bromo-2-(1-methylpropyl) benzene (aryl halide)

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Similar questions

Name the following halides according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:

(i) (CH₃)₂CHCH(Cl)CH₃

(ii) CH₃CH₂CH(CH₃)CH(C₂H₅)Cl

(iii) CH₃CH₂C(CH₃)₂CH₂I

(iv) (CH₃)₃CCH₂CH(Br)C₆H₅

(v) CH₃CH(CH₃)CH(Br)CH₃

(vi) CH₃C(C₂H₅)₂CH₂Br

(vii) CH₃C(Cl)(C₂H₅)CH₂CH₃

(viii) CH₃CH=C(Cl)CH₂CH(CH₃)₂

(ix) CH₃CH=CHC(Br)(CH₃)₂

(x) p-ClC₆H₄CH₂CH(CH₃)₂

(xi) m-ClCH₂C₆H₄CH₂C(CH₃)₃

(xii) o-Br-C₆H₄CH(CH₃)CH₂CH₃

Name the following halides according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides :

$(C H_{3})_{2} C H C H (C l) C H_{3}$

$C H_{3} C H_{2} C H (C H_{3}) C H (C_{2} H_{5}) C l$

$C H_{3} C H_{2} C (C H_{3})_{2} C H_{2} I$

$(C H_{3})_{3} C C H_{2} C H) (B r) C_{6} H_{5}$

$C H_{3} C H (C H_{3}) C H (B r) C H_{3}$

$C H_{3} C (C_{2} H_{5})_{2} C H_{2} B r$

$C H_{3} C (C l) (C_{2} H_{5}) C H_{2} C H_{3}$

$C H_{3} C H = C (C l) C H_{2} C H (C H_{3})_{2}$

$C H_{3} C H = C H C (B r) (C H_{3})_{2}$

$p - C l C_{6} H_{4} C H_{2} C H (C H_{3})_{2}$

$m - C l C H_{2} C_{6} H_{4} C H_{2} C (C H_{3})_{3}$

$o - B r - C_{6} H_{4} C H (C H_{3}) C H_{2} C H_{3}$

Write the IUPAC name of the following compounds:

{({C H}_{3})}_{2} C H C H (C l) {C H}_{3}

ii)

{C H}_{3} {C H}_{2} C {({C H}_{3})}_{2} {C H}_{2} I

iii)

{C H}_{3} C H ({C H}_{3}) C H (B r) {C H}_{3}

iv)

{C H}_{3} C (C l) (C_{2} H_{5}) {C H}_{2} {C H}_{3}

{C H}_{3} C H = C H C (B r) {({C H}_{3})}_{2}

Q. Name the following compounds according to IUPAC system of nomenclature:
(i)

C H_{3} C H (C H_{3}) C H_{2} C H_{2} C H O

(ii)

C H_{3} C H_{2} C O C H (C_{2} H_{5}) C H_{2} C H_{2} C l

(iii)

C H_{3} C H = C H C H O

(iv)

C H_{3} C O C H_{2} C O C H_{3}

(v)

C H_{3} C H (C H_{3}) C H_{2} C (C H_{3})_{2} C O C H_{3}

(vi)

(C H_{3})_{3} C C H_{2} C O O H

(vii)

O H C C_{6} H_{4} C H O - p

Q. Write IUPAC names of the following compounds and classify them into primary, secondary and tertiary amines.
(i)

(C H_{3})_{2} C H N H_{2}

(ii)

C H_{3} (C H_{2})_{2} N H_{2}

(iii)

C H_{3} N H C H (C H_{3})_{2}

(iv)

(C H_{3})_{3} C N H_{2}

(v)

C_{6} H_{5} N H C H_{3}

(iv)

(C H_{3} C H_{2})_{2} N C H_{3}

(vii)

m - B r C_{6} H_{4} N H_{2}

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