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Question

Name the following halides according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:
i) (CH3)2CHCH(Cl)CH3 ii) CH3CH2CH(CH3)CH(C2H5)Cl
iii) CH3CH2C(CH3)2CH2I iv) (CH3)3CCH2CH(Br)C6H5
v) CH3CH(CH3)CH(Br)CH3 vi) CH3C(C2H5)2CH2Br
vii) CH3C(Cl)(C2H5)CH2CH3 viii) CH3CH=C(Cl)CH2CH(CH3)2
ix) CH3CH=CHC(Br)(CH3)2 x) pClC6H4CH2CH(CH3)2
xi) mClCH2C6H4CH2C(CH3)3 xii) oBrC6H4CH(CH3)CH2CH3

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Solution

The IUPAC names of various compounds are given below in order:

(1) 2-Chloro-3-methylbutane (secondary alkyl halide)
(ii) 3-Chloro-4-methylhexane (secondary alkyl halide)
(iii) 1-Iodo-2,2-dimethylbutane (primary alkyl halide)
(iv) 1-Bromo-3,3-dimethyl-1-phenylbutane (secondary benzyl halide)
(v) 2-Bromo-3-methylbutane (secondary alkyl halide)
(vi) 1-Bromo-2-ethyl-2-methylbutane (primary alkyl halide)
(vii) 3-Chloro-3-methylpentane (tertiary alkyl halide)
(viii) 3-Chloro-5-methylhex-2-ene (vinyl halide)
(ix) 4-Bromo-4-methylpent-2-ene (allyl halide)
(x) 1-Chloro-4-(2-methylpropyl) benzene (aryl halide)
(xi) 1-Chloromethyl-3-(2,2-dimethylpropyl) benzene (primary benzyl halide)
(xii) 1-Bromo-2-(1-methylpropyl) benzene (aryl halide)

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