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Question

Name the most stable ion and explain why.


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Solution

Ions:

  • Ions may be an element, a molecule, or a chemical compound with a definite amount of charge.
  • In other words, an ion is a chemically charged species.
  • An ion may either be positively or negatively charged.

Stability of an ion:

  • The stability of an ion depends upon many factors such as electronic configuration, number of bonds, electronegativity of the bonded atom, structure of the ion, aromaticity, resonance, hyperconjugation, etc.
  • The most stable ion is the tertiary carbonium ion because of the presence of 9 α- hydrogens.
  • Hyperconjugation is a dominating factor when there are than 6 α- hydrogens.
Assertion: Tertiary carbonium ions are generally formed more easily than  primary carbonium ions. Reason: Hyperconjugation as well as inductive  effect due to additional alkyl groups stabilize tertiary carbonium ions.
  • This makes this ion the most stable ion.

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