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Question

Name the products formed and give appropriate chemical equations for the following:

  1. Sodium reacting with ethyl alcohol
  2. Ethanol oxidized by acidified potassium dichromate.

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Solution

Chemical equations are symbolic representations of chemical processes that express the reactants and products in terms of their chemical formulas.

(a) With the emission of hydrogen gas (H2), the Sodium (Na) metal combines with Ethyl alcohol (C2H5OH) to produce Sodium ethanoate (C2H5ONa) as a primary product. Because Sodium (Na) is a highly reactive metal, it produces heat as it reacts, making it an exothermic reaction. Chemical equation for the above is given as

C2H5OH(aq)Ethylalcohol+Na(s)SodiumC2H5ONaSodiumethanoate+H2(g)Hydrogen

Ethanol (C2H5OH) interacts with Sodium (Na) to generate sodium Ethanoate (C2H5ONa) and Hydrogen gas (H2) in this process.

(b) Ethanol is an alcohol. It's also known as ethyl alcohol. It has two carbon (C) atoms in the ethyl group and one in the hydroxyl group.
Potassium dichromate (K2Cr2O7) that has been acidified is a powerful oxidizer. It converts Ethanol (C2H5OH) to acetaldehyde (CH3CHO) by oxidizing it.
Ethanal is the IUPAC term for Acetaldehyde (CH3CHO). A molecule of hydrogen is lost during the oxidation of ethanol to ethanal, and a Carbon (C)-Oxygen (O2) single bond is transformed to a Carbon-Oxygen double bond (C=O). The hydroxyl group of alcohol is transformed to the carbonyl group of aldehyde during this reaction.
In the presence of acidified Potassium dichromate (K2Cr2O7), the oxidation of Ethanol (C2H5OH) does not halt at the aldehyde stage. Ethanal (C2H5OH) is transformed to Ethanoic acid (CH3COOH) after additional oxidation. Chemical equation for the above is given as

C2H5OH(aq)Ethylalcohol+K2Cr2O7/H+AcidifiedPotassiumdichromateCH3CHO(l)AcetaldehydeCH3COOH(l)Ethanoicacid


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