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Isomerism in Coordination Compounds

Name the type...

Question

Name the types of isomerism shown by the following pairs of compounds:
(i) $[C o C l (H_{2} O) (N H_{3})_{4} C l_{2}]$ and $[C o C l_{2} (N H_{3})_{4}] C l \cdot H_{2} O$
(ii) $[P t (N H_{3})_{4}] [P t C l_{6}]$ and $[P t (N H_{3})_{4} C l_{2}] [P t C l_{4}]$

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Solution

(i) Hydrate isomerism.
(ii) Coordination isomerism.

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Similar questions

Q. Name the types of isomerism shown by the following pairs of compounds:
(i)

[C u {(N H_{3})}_{4}] [P t {C l}_{4}]

[P t {(N H_{3})}_{4}] [C u {C l}_{4}]

{[C o {(P n)}_{2} {C l}_{2}]}^{+}

{[C o {(t n)}_{2} {C l}_{2}]}^{+}

Q. The complexes

[P t {(N H_{3})}_{4}] [P t C l_{6}]

[P t {(N H_{3})}_{4} C l_{2}] [P t C l_{4}]

Give the iupac names

[Pt(NH3)4][PtCl4]

[Pt(NH3)4Cl2][PtCl4]

Q. Which one of the following pairs of isomers and types of isomerism are correctly matched?
(i)

[C o (N H_{3})_{5} (N O_{2})] C l_{2}

[C o (N H_{3})_{5} (O N O) C l_{2} . . . (L i n k a g e)

[C u (N H_{3})_{4}] [P t C l_{4}]

[P t (N H_{3})_{4}] [C u C l_{4}] . . . (C o o r d i n a t i o n)

[P t C l_{2} (N H_{3})_{4}] B r_{2}

[P t B r_{2} (N H_{3})_{4}] C l_{2} . . . (I o n i z a t i o n)

Select the correct answer using the codes given below:

Q. Write IUPAC name of the following compounds:

[P t (N H_{3})_{4} C l_{2}] [P t C l_{4}]

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