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Question

NaNO2+ABN2

A+AgNO3 White ppt soluble in C

ANaOH,Δ−−−−C
Hence, A is :

A
NaCl
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B
NH4Cl
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C
NH4NO2
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D
NH4NO3
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Solution

The correct option is B NH4Cl
Sodium nitrite reacts with ammonium chloride forms ammonium nitrate which on heating produces nitrogen.
NaNO2+NH4ClNaCl+NH4NO2heatH2O+N2..
Ammonium chloride reacts with silver nitrate to produce white ppt of silver chloride which is soluble in ammonia (compound C).
NH4Cl+AgNO3NH4NO3+AgCl

AgCl+2NH3Ag(NH3)2Cl(soluble).

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