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Question

Nitrogen gas is at temperature300°C. The temperature (in K) at which the rms speed of a H2 molecule would be equal to the rms speed of a nitrogen molecule is


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Solution

Step 1. Given data:

  1. The temperature of nitrogen gasTN=300C

Step 2. Formula used:

The r.m.sspeed for gas isvrms=3RTM where, R=universalgasconstant,M=molecularmass

Step 3. Calculating the temperature at which ther.m.s speed of hydrogen will be equal to ther.m.s speed of nitrogen gas.

According to the given question,

Let at the temperatureTH of hydrogen, ther.m.s speed of hydrogen will be equal to ther.m.s speed of nitrogen gas.

For hydrogen vrms=3RTHMHMH=Molecular mass of hydrogen molecule

For nitrogen vrms=3RTNMNMN=Molecular mass of nitrogen molecule

now,

3RTHMH=3RTNMNTHMH=TNMNTH=TNMNMHNow,TN=300C+273K=573KTH=57328×2=40·92Kas,MN=28,MH=2

Thus the temperature of hydrogen gas is40·92K.


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