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Synthesis of Esters from Acid Chlorides and Anhydrides

Nucleophilic ...

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Nucleophilic substitution of acid derivatives with ammonia or amine is called ammonolysis.

A

True

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B

False

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Q. What is the order of the decreasing reactivity for the carboxylic acid derivatives given above, in a nucleophilic substitution reaction?

Q. The relative rate of nucleophilic acyl substitution for a given acid derivative (RCOX) depends on :

Q. Acid anhydride undergoes nucleophilic substitution at a faster rate than ethyl acetate primarily because :

Q. Nucleophilic substitution of acid derivatives with ammonia or amine is called ammonolysis.

Q. Acid derivatives can be represented by

(except cyanide) and can be formed by nucleophilic acyl substitution in carboxylic acids.
Reaction of acid derivatives with a nucleophile can be explained by following mechanism:

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Synthesis of Esters from Acid Chlorides and Anhydrides

Standard XII Chemistry