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Question

On the basis of LCAO – MO theory the magnetic characteristics of N2 and N+2 are:

A
Both diamagnetic
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B
Both paramagnetic
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C
N2 diamagnetic and N+2 paramagnetic
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D
N2 paramagnetic and N+2 diamagnetic
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Solution

The correct option is C N2 diamagnetic and N+2 paramagnetic
N2(14): σ1s2σ1s2 σ2s2σ2s2 π2p2x π2p2y σ2p2z DiamagneticN+2(13): σ1s2σ1s2 σ2s2 σ2s2π2p2x π2p2y σ2p1z Paramagnetic

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