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Question

One mole of an ideal gas is taken from a to b along two paths denoted by the solid and the dashed lines as shown in the graph below. If the work done along the solid line path is Ws and that along the dotted line path is Wd then the integer closest to the ratio WdWs is:___

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Solution

Work done along dashed path |W|=p ΔV=4×1.5+1×1+23×2.5=8.65L atm
Work done along solid path W=nRT In v2v1=p1 V1 In V2V1
=2×2.3 log 5.50.5=2×2.3 log 11=4.79
WdWs=8.654.79=1.802

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