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Question

One of the reaction that takes place to producing steel from iron ore is the reduction of iron(III) oxide by carbon monoxde to give iron metal and CO2
FeO(s)+CO(g)Fe(s)+CO2(g);Kp=0.265
What are the equilibrium partial pressures of CO and CO2 at 1050K if the initial partial pressures are: pCO=1.4atm and pCO2=0.80atm?

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Solution

FeO(s)+CO(g)Fe(s)+CO2(g)
at t=0 1.4 atm 0.8 atm
Kp=0.265
Qp=PCO2PCO
Qp=0.81.4=0.571
Kp<Qp, the reaction proceeds in reverse direction
CO2 pressure decreases and that of CO increases.
PCO2=(0.8P)Kp=PCO2PCO0.265=(0.8P)(1.4+P)
P=0.339 atm
At eqb.
PCO2=0.80.339=0.461atmPCO=1.40+0.339=1.739atm

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