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Question

Optical isomerism is exhibited by:

(ox = oxalate anion; en = ethylenediamine).

A
cis[CrCl2(ox)2]3
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B
[Co(en)3]3+
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C
trans[CrCl2(ox)2]3
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D
[Co(ox)(en)2]+
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Solution

The correct options are
A [Co(en)3]3+
B cis[CrCl2(ox)2]3
C [Co(ox)(en)2]+
Optical isomerism is exhibited by the complexes cis[CrCl2(ox)2]3, [Co(en)3]3+ and [Co(ox)(en)2]+.

They can be resolved into d and l isomers.
trans[CrCl2(ox)2]3 is optically inactive as it has a plane of symmetry.

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