Order of reactivity of following acid derivatives towards nucleophilic acyl substitution reactions is
$R - C O C l, R - C O N H_{2}, R - C O O R^{'}, R - C O O C O - R$
(I) (II) (III) (IV)

(II) > (III) > (IV) > (I)

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(IV) > (II) > (I) > (III)

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(III) > (I) > (II) > (IV)

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(I) > (IV) > (III) > (II)

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Solution

The correct option is D (I) > (IV) > (III) > (II)
Based on the order of leaving behaviour of the group.

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In the question arrange the compounds in increasing order of rate of reaction towards nucleophilic substitution.

(a) (iii) < (ii) < (i) (b) (ii) < (iii) < (i)

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