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B
IV>III>I>II
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C
IV>I>II>III
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D
IV>III>II>I
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Solution
The correct option is BIV>III>I>II The carbocation(IV) is resonance stabilized and hence is the most stable. Among primary, secondary and tertiary carbocations, tertiary is the most stable while primary is the least stable due to decreasing −I effect of the methyl group. Hence the order of stability of the carbocation is as follows