The correct option is D Boric oxide
Orthoboric acid, H3BO3 is a white crystalline solid, with soapy touch. It is sparingly soluble in water but highly soluble in hot water.
On heating, orthoboric acid above 370 K forms metaboric acid, HBO2 which on further heating yields boric oxide, B2O3.
H3BO3100∘C⟶HBO2Δ⟶B2O3
Hence correct option is d.