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Question

Oxalic acid is heated with concentrated H2SO4. When the resultant gases are passed over red hot carbon, X is obtained. Here, X is:

A
CO
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B
CH4
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C
CO2
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D
C2H4
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Solution

The correct option is C CO
(COOH)2+H2SO4(l)H2O+CO2(g)+CO(g)+H2SO4(l)

When oxalic acid is heated with conc. sulfuric acid, a mixture of CO and CO2 is obtained.

H2C2O4H2SO4−−−H2OCO+CO2

When this mixture is passed over red hot carbon, CO2 is reduced to CO.

CO+CO2CΔ3CO

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