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Question

Oxidising power of ClO−, ClO−2,ClO−3, ClO−4 is :

A
ClO4>ClO2>ClO3>ClO
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B
ClO2>ClO>ClO3>ClO4
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C
ClO<ClO2<ClO3<ClO4
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D
ClO3>ClO2>ClO>ClO4
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Solution

The correct option is C ClO<ClO2<ClO3<ClO4
Order of oxidation power: ClO<ClO2<ClO3<ClO4 because the oxidation states of chloride in ClO,ClO2,ClO3 and ClO4 are +1,+3,+5 and +7 respectively.
So, ClO4 with highest oxidation state can easily oxidise and in turn get reduced.

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