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Question

0.456 gram of an organic compound (Molecular mass = 100u) is dissolved in 31.14 grams of acetone. Calculate the boiling point of solution if Kb= 17.2 and boiling point of acetone = 56.2 degree Celsius.

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Solution

First calculate the elevation in boiling point,

ΔTb = (Kf x wb x 1000) / (MB x wA)

wb = 0.45 g

wA = 31.14 g

MB = 100 x 1.66 x 10-24 g.

ΔTb = Tb' - Tb

Tb' = ΔTb + Tb


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