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Question

PA= partial pressure of component A in liquid mixture.
PoA= vapour pressure of A.
χA = mole fraction of A in liquid mixture.

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Solution

(A) C2H5OH+H2O forms azeotropic mixture at a particular composition. It is a non ideal solution and shows positive deviation from Raoult's law.
(B) C2H5Br+C2H5I forms an ideal solution and obeys Raoult's law.
(C) PA=PoAχA forms an ideal solution and obeys Raoult's law.
(D) H2O+H2SO4 forms azeotropic mixture at a particular composition. It is a non ideal solution and shows negative deviation from Raoult's law.

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