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Structure and Physical Properties of Ethers

Chlorine is m...

Question

Chlorine is more electronegative than oxygen but still oxygen forms hydrogen bond but chlorine does not form hydrogen bond??

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Solution

Inspite of being sufficiently electronegative atom chlorine can not form Hydrogen bonding as that of oxygen becuase of it's ;arge size.
Due to it's large size,polaristaion due to hydrogen atom is large and thus it ends up forming polar bond. Thus Chlorine becomes poor hydrogen acceptor.

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Explain why inspite of nearly the same electronegativity, oxygen forms hydrogen bonding while chlorine does not.

Q. "Though nitrogen and chlorine have almost equal electronegativity values, nitrogen forms hydrogen bonding while chlorine does not". This is due to:

B C l_{3}

does not exist as a dimer but

B H_{3}

exists as a dimer because:

Q. Carbon forms covalent bonds with itself and other elements such as hydrogen, oxygen, sulphur, nitrogen and chlorine.

Oxygen is more electronegative than chlorine. In the series of oxyacids HOCl,

H C l O_{2}

H C l O

H C l O_{4}

an increasing number of oxygen atom are bonded to the chlorine atom.

Chlorine forms a number of oxyacids which differ in their strengths. The conjugate base of these acids also differs in their stability order.

The hybridization of Cl in

C l O_{2}^{-}

and its shape are :

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