in a crystalline solid having formula A2B,anions B are arranged cubic close packing lattice and cation A are equally distributed between octahedral voids and tetrahedral voids
a)what % of octahedral voids is occupied?
b)what %of tetrahedral voids is occupied?
In this A2B type structure (or antifluorite structure), Anions (B) have ccp arrangement. Cations (A) occupy all the tetrahedral voids. This structure has 4 : 8 coordination.
Percentage of tetrahedral voids occupied =8/8 × 100 = 100%
Percentage of octahedral voids occupied = 2/4 × 100 = 50%