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Question

in a crystalline solid having formula A2B,anions B are arranged cubic close packing lattice and cation A are equally distributed between octahedral voids and tetrahedral voids

a)what % of octahedral voids is occupied?

b)what %of tetrahedral voids is occupied?

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Solution

In this A2B type structure (or antifluorite structure), Anions (B) have ccp arrangement. Cations (A) occupy all the tetrahedral voids. This structure has 4 : 8 coordination.

Percentage of tetrahedral voids occupied =8/8 × 100 = 100%

Percentage of octahedral voids occupied = 2/4 × 100 = 50%


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