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Abnormal Colligative Properties

P-nitrophenol...

Question

P-nitrophenol is more acidic than o-nitrophenol . But o-nitro benzoic acid is more stronger than p-nitro benzoic acid. Explain

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Q. Which of the following fact(s) explain(s) as to why p-
nitrophenol is more acidic than phenol?
I. - I Effect of nitro group.
II. Greater resonance effect of

p

-nitrophenoxy group
II. Steric effect of bulky nitro group

Benzoic acid is stronger than methanoic acid but weaker than ethanoic acid.

Q. O-nitrophenol is more acidic than O-cresol. Explain.

Explain why p-nitrophenol is more acidic than phenol?

Q. Explain why is ortho nitrophenol more acidic than ortho methoxyphenol?

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