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Byju's Answer
Standard XII
Chemistry
Electrolytic Cell
the redox rea...
Question
The redox reaction in an electrochemical cell is spontaneous or nonspontaneous.
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Solution
Electrolytic cell:
An electrolytic cell is a device that is used to convert electrical energy into chemical energy.
In the electrolytic cell, the redox reaction is not spontaneous and electrical energy has to be supplied to initiate the reaction.
Both the electrodes are placed in the same container in the solution of molten electrolyte.
Here, the anode is positive and the cathode is the negative electrode. The reaction at the anode is oxidation and that at the cathode is reduction.
The external battery supplies the electrons. They enter through the cathode and come out through the anode.
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Assertion :An electrochemical cell can be set-up only if the redox reaction is spontaneous. Reason: A reaction is spontaneous if free energy change is negative.
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An electrolytic cell is one which can convert electrical energy into chemical energy in a non-spontaneous redox reaction.
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