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Question

Phenol and benzoic acid can be distinguished by:

A
aqueous NaHCO3
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B
aqueous NaNO3
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C
aqueous NaOH
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D
conc. H2SO4
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Solution

The correct option is C aqueous NaHCO3
PhenoI and benzoic acid can be distinguished by aqueous NaHCO3.
Phenols are very weak acids. They do not react with weak bases such as sodium hydrogen carbonate.
Benzoic acid is a strong acid. It reacts with sodium hydrogen carbonate to give effervescence of carbon dioxide gas.
C6H5OH+NaHCO3no reaction
PhCOOH+NaHCO3PhCOONa+H2O+CO2

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