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Coordination and Oxidation Number

Potassium hex...

Question

Potassium hexachloroplatinate $K_{2} [P_{2} i C l_{3}]$ adopts anti-fluorite crystal structure. Which of the following ions adopts $f c c$ arrangement?

C l^{-}

ions

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K^{+}

ions

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P t^{4 +}

ions

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[P t C l_{6}]^{2 -}

ions

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Solution

The correct option is D $[P t C l_{6}]^{2 -}$ ions
Solution:- (D) ${[P t {C l}_{6}]}^{2 -}$ ions
Potassium hexachloroplatinate- $K_{2} [P t {C l}_{6}]$
In anti-fluorite crystl structure, the lattice sites are occupied by ${[P t {C l}_{6}]}^{2 -}$ anions.

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